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Catalytic Hydrothiolation: Regio- and Enantioselective Coupling of Thiols and Dienes

Published Web Location

https://doi.org/10.1021/jacs.8b06957
Abstract

We report a Rh-catalyzed hydrothiolation of 1,3-dienes, including petroleum feedstocks. Either secondary or tertiary allylic sulfides can be generated from the selective addition of a thiol to the more substituted double bond of a diene. The catalyst tolerates a wide range of functional groups, and the loading can be as low as 0.1 mol %.

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