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Stability and self-passivation of copper vanadate photoanodes under chemical, electrochemical, and photoelectrochemical operation
- Zhou, Lan;
- Yan, Qimin;
- Yu, Jie;
- Jones, Ryan JR;
- Becerra-Stasiewicz, Natalie;
- Suram, Santosh K;
- Shinde, Aniketa;
- Guevarra, Dan;
- Neaton, Jeffrey B;
- Persson, Kristin A;
- Gregoire, John M
Published Web Location
https://doi.org/10.1039/c6cp00473cAbstract
Deployment of solar fuels technology requires photoanodes with long term stability, which can be accomplished using light absorbers that self-passivate under operational conditions. Several copper vanadates have been recently reported as promising photoanode materials, and their stability and self-passivation is demonstrated through a combination of Pourbaix calculations and combinatorial experimentation.
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