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Open Access Publications from the University of California

Stability and self-passivation of copper vanadate photoanodes under chemical, electrochemical, and photoelectrochemical operation.

  • Author(s): Zhou, Lan
  • Yan, Qimin
  • Yu, Jie
  • Jones, Ryan JR
  • Becerra-Stasiewicz, Natalie
  • Suram, Santosh K
  • Shinde, Aniketa
  • Guevarra, Dan
  • Neaton, Jeffrey B
  • Persson, Kristin A
  • Gregoire, John M
  • et al.

Deployment of solar fuels technology requires photoanodes with long term stability, which can be accomplished using light absorbers that self-passivate under operational conditions. Several copper vanadates have been recently reported as promising photoanode materials, and their stability and self-passivation is demonstrated through a combination of Pourbaix calculations and combinatorial experimentation.

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