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Fullerene-porphyrin constructs.

  • Author(s): Boyd, Peter DW
  • Reed, Christopher A
  • et al.

Published Web Location

https://doi.org/10.1021/ar040168f
Abstract

Porphyrins and fullerenes are spontaneously attracted to each other. This new supramolecular recognition element can be used to construct discrete host-guest complexes, as well as ordered arrays of interleaved porphyrins and fullerenes. The fullerene-porphyrin interaction underlies successful chromatographic separations of fullerenes, and there are promising applications in the areas of porous framework solids and photovoltaic devices.

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