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The Use of Heterometallic Bridging Moieties To Generate Tractable Lanthanide Complexes of Small Ligands

  • Author(s): Evans, WJ;
  • Anwander, R;
  • Doedens, RJ;
  • Ziller, JW
  • et al.
Abstract

Hexane‐soluble derivatives of neodymium amide Nd‐(NMe2)3 such as 1 or the unsolvated heterometallic peralkyl compound 2 form in the reaction of MMe3 (M = Al, Ga) with 3. This provides a route to soluble lanthanide complexes with small ligands. (Formula Presented.) (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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