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Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N(3)P(3)Cl(6)] catalyzed by silylium ions.

  • Author(s): Zhang, Yun
  • Huynh, Keith
  • Manners, Ian
  • Reed, Christopher A
  • et al.

Published Web Location

https://doi.org/10.1039/b713933k
Abstract

The temperature required for ring-opening polymerisation of cyclo-N(3)P(3)Cl(6) can be dramatically lowered by employing trialkylsilylium carboranes [R(3)Si(CHB(11)X(11)] as catalysts.

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