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Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N(3)P(3)Cl(6)] catalyzed by silylium ions.
- Author(s): Zhang, Yun
- Huynh, Keith
- Manners, Ian
- Reed, Christopher A
- et al.
Published Web Locationhttps://doi.org/10.1039/b713933k
The temperature required for ring-opening polymerisation of cyclo-N(3)P(3)Cl(6) can be dramatically lowered by employing trialkylsilylium carboranes [R(3)Si(CHB(11)X(11)] as catalysts.