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Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N 3 P 3 Cl 6 ] catalyzed by silylium ions

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The temperature required for ring-opening polymerisation of cyclo-N(3)P(3)Cl(6) can be dramatically lowered by employing trialkylsilylium carboranes [R(3)Si(CHB(11)X(11)] as catalysts.

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