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Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N(3)P(3)Cl(6)] catalyzed by silylium ions.
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https://doi.org/10.1039/b713933kAbstract
The temperature required for ring-opening polymerisation of cyclo-N(3)P(3)Cl(6) can be dramatically lowered by employing trialkylsilylium carboranes [R(3)Si(CHB(11)X(11)] as catalysts.
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