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Hydrogren-Bonding between Thioacetamide and Some N,N-dimethylalkylamides in Chloroform.

  • Author(s): Park, Hee-Suk;
  • Choi, Jae-Young;
  • Kim, Young-Ae;
  • Huh, Young-Duk;
  • Yoon, Chang-Ju;
  • Choi, Young-Sang
  • et al.
Creative Commons 'BY' version 4.0 license
Abstract

The near-IR spectra of thioacetamide were recorded for the investigation of hydrogen bonding between thioacetamide (TA) and N,N-dimethylalkylamides (DMF, OMA, DMP) in chloroform over the range of 5°C to 55°C. The v0 + amide II combination band has been resolved into contributions from monomeric TA, 1:1 hydrogen bonded complex and 1:2 complex by the parameterized matrix modeling method. The association constants

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