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Is cement a glassy material?

  • Author(s): Bauchy, M
  • Abdolhosseini Qomi, MJ
  • Pellenq, RJM
  • Ulm, FJ
  • et al.
Creative Commons Attribution 4.0 International Public License
Abstract

The nature of Calcium-Silicate-Hydrate (C-S-H), the binding phase of cement, remains a controversial question. In particular, contrary to the former crystalline model, it was recently proposed that its nanoscale structure was actually amorphous. To elucidate this issue, we analyzed the structure of a realistic simulation of C-S-H, and compared the latter to crystalline tobermorite, a natural analogue to cement, and to an artificial ideal glass. Results clearly support that C-S-H is amorphous. However, its structure shows an intermediate degree of order, retaining some characteristics of the crystal while acquiring an overall glass-like disorder. Thanks to a detailed quantification of order and disorder, we show that its amorphous state mainly arises from its hydration. © 2014 Taylor & Francis Group.

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