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Cascade rearrangement of furylcarbinols with hydroxylamines: practical access to densely functionalized cyclopentane derivatives.

  • Author(s): Veits, Gesine K;
  • Wenz, Donald R;
  • Palmer, Leoni I;
  • St Amant, André H;
  • Hein, Jason E;
  • Read de Alaniz, Javier
  • et al.
Abstract

This article describes the aza-Piancatelli rearrangement with hydroxylamines to 4-aminocyclopentenones and subsequent transformations that highlight the versatility of the cyclopentene scaffold and the value of the hydroxylamine nucleophile in this transformation.

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