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Evidence for CH Hydrogen Bonding in Salts of tert‐Butyl Cation
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https://doi.org/10.1002/anie.201203958Abstract
Environmentally sensitive: A combination of C-H anion hydrogen bonding and hyperconjugative charge delocalization explains the sensitivity of the IR spectrum of the tert-butyl cation to its anion (see high-resolution X-ray structure with a CHB(11)Cl(11)(-) counterion). The νCH vibration of the cation scales linearly with the basicity of carborane anions on the νNH scale. The same also holds for the C(6)H(7)(+) benzenium ion.
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