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A novel cationic heteropolyoxovanadium( iv ) cluster functionalized with organic ligands : synthesis and characterization of the fully reduced species [Mn II V IV 6 O 6 {(OCH 2 CH 2 ) 2 N(CH 2 CH 2 OH)} 6 ]Cl 2
Abstract
The solvothermal reaction of (HOCH2CH2)3N with [(n-C4H9)4N]3[H3V10O28] and MnCl2 x 4H2O in CH3CN and CH3OH yields a novel cationic heteropolyoxovanadium(IV) cluster, [Mn(II)V(IV)6O6[(OCH2CH2)2N(CH2CH2OH)]6]2+, containing a fully reduced new cyclic [MnV6N6O18] core with the Anderson structure.
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