Skip to main content
eScholarship
Open Access Publications from the University of California

Direct synthesis of anilines and nitrosobenzenes from phenols.

  • Author(s): St Amant, AH
  • Frazier, CP
  • Newmeyer, B
  • Fruehauf, KR
  • Read de Alaniz, J
  • et al.
Abstract

A one-pot synthesis of anilines and nitrosobenzenes from phenols has been developed using an ipso-oxidative aromatic substitution ((i)SOAr) process. The products are obtained in good yields under mild and metal-free conditions. The leaving group effect on reactions that proceed through mixed quionone monoketals has also been investigated and a predictive model has been established.

Many UC-authored scholarly publications are freely available on this site because of the UC Academic Senate's Open Access Policy. Let us know how this access is important for you.

Main Content
Current View