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Open Access Publications from the University of California

Oxidation and crystal field effects in uranium

  • Author(s): Tobin, JG;
  • Yu, SW;
  • Booth, CH;
  • Tyliszczak, T;
  • Shuh, DK;
  • Van Der Laan, G;
  • Sokaras, D;
  • Nordlund, D;
  • Weng, TC;
  • Bagus, PS
  • et al.

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An extensive investigation of oxidation in uranium has been pursued. This includes the utilization of soft x-ray absorption spectroscopy, hard x-ray absorption near-edge structure, resonant (hard) x-ray emission spectroscopy, cluster calculations, and a branching ratio analysis founded on atomic theory. The samples utilized were uranium dioxide (UO2), uranium trioxide (UO3), and uranium tetrafluoride (UF4). A discussion of the role of nonspherical perturbations, i.e., crystal or ligand field effects, will be presented.

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