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Engineering Auger recombination in colloidal quantum dots via dielectric screening.

  • Author(s): Hou, Xiaoqi
  • Kang, Jun
  • Qin, Haiyan
  • Chen, Xuewen
  • Ma, Junliang
  • Zhou, Jianhai
  • Chen, Liping
  • Wang, Linjun
  • Wang, Lin-Wang
  • Peng, Xiaogang
  • et al.
Abstract

Auger recombination is the main non-radiative decay pathway for multi-carrier states of colloidal quantum dots, which affects performance of most of their optical and optoelectronic applications. Outstanding single-exciton properties of CdSe/CdS core/shell quantum dots enable us to simultaneously study the two basic types of Auger recombination channels-negative trion and positive trion channels. Though Auger rates of positive trion are regarded to be much faster than that of negative trion for II-VI quantum dots in literature, our experiments find the two rates can be inverted for certain core/shell geometries. This is confirmed by theoretical calculations as a result of geometry-dependent dielectric screening. By varying the core/shell geometry, both types of Auger rates can be independently tuned for ~ 1 order of magnitude. Experimental and theoretical findings shed new light on designing quantum dots with necessary Auger recombination characteristics for high-power light-emitting-diodes, lasers, single-molecular tracking, super-resolution microscope, and advanced quantum light sources.

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