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Improving LMOF luminescence quantum yield through guest-mediated rigidification
- Author(s): Lustig, William P
- Teat, Simon J
- Li, Jing
- et al.
Published Web Locationhttps://doi.org/10.1039/c9tc05216j
Rotation of a specific pyridyl ring in LMOF-236 is locked by loading guest molecules into the MOF's pore, improving quantum yield by nearly 400%–an example of a generalizable strategy for maximizing quantum yield via guest-packing rigidification.