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Open Access Publications from the University of California

The template effect of a SiF 6 2− guest drives the formation of a heteroleptic Fe( ii ) coordination helicate


The anion SiF62- exerts a strong template effect, driving the exclusive assembly of two different bispyridylpyrazolyl ligands into a triple stranded Fe(II) dinuclear heteroleptic helicate, engendering a new class within the large family of coordination helicates.

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