Radiation Controllable Synthesis of Robust Covalent Organic Framework Conjugates for Efficient Dynamic Column Extraction of 99TcO4−
Published Web Locationhttps://doi.org/10.1016/j.chempr.2020.08.005
Wang et al. report here an ultra-robust imidazolium-decorated covalent organic framework (COF) conjugate fabricated by an ionizing radiation strategy for efficient capture of 99TcO4−, where tunable ReO4− uptake up to 952 mg g−1 can be achieved by simply adjusting the γ-ray dose. The COFs feature high porosity, ultra-robust nanofiber structure, and fast adsorption kinetics, thus emphasizing their advantages in terms of column experiments.