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Temperature-induced amorphization in CaCO3 at high pressure and implications for recycled CaCO3 in subduction zones.

  • Author(s): Hou, Mingqiang
  • Zhang, Qian
  • Tao, Renbiao
  • Liu, Hong
  • Kono, Yoshio
  • Mao, Ho-Kwang
  • Yang, Wenge
  • Chen, Bin
  • Fei, Yingwei
  • et al.
Abstract

Calcium carbonate (CaCO3) significantly affects the properties of upper mantle and plays a key role in deep carbon recycling. However, its phase relations above 3 GPa and 1000 K are controversial. Here we report a reversible temperature-induced aragonite-amorphization transition in CaCO3 at 3.9-7.5 GPa and temperature above 1000 K. Amorphous CaCO3 shares a similar structure as liquid CaCO3 but with much larger C-O and Ca-Ca bond lengths, indicating a lower density and a mechanism of lattice collapse for the temperature-induced amorphous phase. The less dense amorphous phase compared with the liquid provides an explanation for the observed CaCO3 melting curve overturn at about 6 GPa. Amorphous CaCO3 is stable at subduction zone conditions and could aid the recycling of carbon to the surface.

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