Lawrence Berkeley National Laboratory

Many-body systems in nature exhibit complexity and self-organization arising from seemingly simple laws. The long-range Coulomb interaction between electrical charges generates a plethora of bound states in matter, ranging from the hydrogen atom to complex biochemical structures. Semiconductors form an ideal laboratory for studying many-body interactions of quasi-particles among themselves and with lattice vibrations and light. Oppositely charged electron and hole quasi-particles can coexist in an ionized but correlated plasma, or form bound hydrogen-like pairs called excitons which strongly affect physical properties. The pathways between such states however remain elusive in near-visible optical experiments that detect a subset of excitons with vanishing center-of-mass momenta. In contrast, transitions between internal exciton levels which occur in the far-infrared at terahertz (10 ^{s) frequencies are in dependent of this restriction suggesting their use as a novel probe of pair dynamics. Here, we employ an ultrafast terahertz probe to directly investigate the dynamical interplay of optically-generated excitons and unbound electron-hole pairs in GaAs quantum wells. Our observations witness an unexpected quasi-instantaneous excitonic enhancement, reveal formation of insulating excitons on a hundred picosecond timescale and manifest conditions under which excitonic populations prevail.}